Product ID:M9015, MALACHITE GREEN OXALATE, CERTIFIED
MSDS Date:07/13/1999
FSC:6910
NIIN:01-188-9759
Status Code:A
MSDS Number: CLDSZ

Emergency Phone: 314-771-5765

Info Phone: 314-771-5765

Cage: JO751

Telephone: 314-771-5765

Cage: JO751

MALACHITE GREEN OXALATE

CAS: 2437-29-8

RTECS: BQ1190000

LD50 LC50 Mixture:LD50: ORAL (RAT)= 275 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED. MAY BE
HARMFUL IF INHALED. MAY BE HARMFUL IF ABSORBED THROUGHT THE SKIN.
CAUSES SEVERE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MATERIAL
MAY BE IRRITATING TO MUCOUS MEMB RANES AND UPPER RESPIRATORY TRACT.
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL AND
TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Explanation of Carcinogenicity:NOT PROVIDED BY MFR
Effects of Overexposure:NOT PROVIDED BY MFR
Medical Cond Aggravated by Exposure:NOT PROVIDED BY MFR

First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. IN INHALED, REMOVE TO FRESH AIR.
IF NOT GREATHI NG, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER
PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED
CLOTHING BEFORE REUSE .

Flash Point:NOT PROVIDED BY
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, WATER SPRAY
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR SELF CONTAINED BREATHING APPARATUS,
RUBBER BOOTS AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND
HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND
WASH SPILL SITE AFTER MATERI AL PICKUP IS COMPLETE.
Neutralizing Agent:NOT PROVIDED BY MFR

Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
WASH THOROUGHLY AFTER HANDLING. TOXIC. SEVERE EYE IRRITANT. KEEP
TIGHTLY CLOSED. STORE IN A COOL DR Y PLACE.
Other Precautions:NOT PROVIDED BY MFR

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:OTHER PROTECTIVE CLOTHING. SAFETY SHOWER AND
EYE BATH.
Work Hygienic Practices:NOT PROVIDED BY MFR
Supplemental Safety and Health
NOT PROVIDED BY MFR

HCC:T6
Boiling Pt:=164.C, 327.2F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED BY MFR
Decomp Temp:Decomp Text:NOT PROVIDED BY MFR
Vapor Pres:NOT PROVIDED BY MFR
Vapor Density:NOT PROVID
Spec Gravity:NOT PROVIDED BY MFR
pH:NOT PROVIDED
Viscosity:NOT PROVIDED BY MFR
Evaporation Rate & Reference:NOT PROVIDED BY MFR
Solubility in Water:NOT PROVIDED BY MFR
Appearance and Odor:GREEN CRYSTALLINE POWDER
Percent Volatiles by Volume:NOT PROVIDED
Corrosion Rate:NOT PROVIDED BY MFR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NOT PROVIDED BY MFR
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
NITROGEN OXIDES
Conditions to Avoid Polymerization:WILL NOT OCCUR

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Toxicological Information:IRRITATION DATA: EYE-RBT 76 MG/KG SEV.
TARGET ORGAN DATA: BEHAVIORAL (CHANGE IN MOTOR ACTIVITY),
GASTROINTESTINAL (HYPERMOTILITY, DIARRHEA), GASTROINTESTINAL (OTHER
CHANGES). ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL
SUBSTANCES (RTECS) DATA IS PRESENTED HERE.

Ecological:DATA NOT YET AVAILABLE.

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.

SARA Title III Information:THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.